ABSTRACT
The present paper describes the determination of trace Ni, Fe, Mo, Mn and B in Ti/TiC composite material using carbon powder, calcium carbonate, cupric oxide and beryllium oxide-as buffer by atomic emission spectrometry (ASE). Be 298.61 nm was selected as internal standard line. Sample separation and chemistry treatment were not requirel. The sample was directly loaded into ordinary electrode. The method is simple, rapid and accurate. The requirement of determination, and factors of influence were studied. A new method has developed for the determination of Ni, Fe, Mo, Mn and B. The analysis lines of Ni, Fe, Mo, Mn and B are 300.36, 248.33, 315.82, 260.57 and 249.68 nm respectively. The internal standard line of Be is 298.61 nm. The linear ranges of the determination of Ni, Fe, Mo, Mn and B are 0.003%-0.30%, 0.001%-0.20%, 0.003%-0.30%, 0.001%-0.20%, 0.001%-0.20% respectively. The detection limits of Ni, Fe, Mo, Mn and B are 0.003%; 0.001%, 0.003%, 0.001% and 0.001% respectively. The ranges of the recovery of Ni, Fe, Mo, Mn and B are 95.80%-104.8%, and the standard relative deviations (RSD) are less than 5.0% (n = 9). The method has been applied to the determination of Ni, Fe, Mo, Mn and B with satisfactory results.
ABSTRACT
The present paper shows that the trace amount of gold, platinum and palladium in hydrochloric acid solution can be concentrated by hyperbranched polymer. The new reagent has a rapid adsorption rate and big concentrating capacity. The determination of trace Au, Pt and Pd in sample using carbon powder and strontium carbonate as buffer was carried out by atomic emission spectrometry(AES). Zirconium was selected as internal standard line. The sample was directly loaded into ordinary electrode. The method is simple, rapid and accurate. The condition of determination, and factors of influence were studied. The analysis line of Au, Pt and Pd is 312.3, 306.5 and 311.4 nm respectively. The internal standard line of Zr is 310.7 nm. The linear range of the determination of Au, Pt and Pd is 0-0. 20%, 0-0. 40% and 0-0. 20% respectively. The detection limit of Au, Pt and Pd is 0.010%, 0.0030% and 0.0030% respectively. The method has been applied to the determination of Au, Pt and Pd with satisfactory results.
ABSTRACT
This paper describes the determination of trace La, Ce, Pr, Nd, Sm, Gd, Tb, Dy, Yb and Lu in the sample, using carbon powder, potassium sulfate, barium sulfate, strontium sulfate, and scandium chloride as buffer, by atomic emission spectrometry (AES). Scandium was selected as internal standard line. Sample separation and chemical treatment were not required. The sample was directly loaded into ordinary electrode. The method is simple, rapid and accurate. The determination requirement and influence factors were studied. A new method was developed for the determination of ten rare earth elements, for which the detection limit is smaller than 0.030%, and the range of the recovery is 94%-105%. The results of these elements in standard sample are in agreement with certified values, and the RSD is smaller than 5% (n = 9). The method has been applied to the determination of ten rare earth elements with satisfactory results.
Subject(s)
Metals, Rare Earth/analysis , Spectrophotometry, Atomic/methods , Barium Sulfate/chemistry , Buffers , Carbon/chemistry , Cerium/analysis , Cerium/chemistry , Dysprosium/analysis , Dysprosium/chemistry , Electrodes , Gadolinium/analysis , Gadolinium/chemistry , Lanthanum/analysis , Lanthanum/chemistry , Lutetium/analysis , Lutetium/chemistry , Metals, Rare Earth/chemistry , Metals, Rare Earth/standards , Neodymium/analysis , Neodymium/chemistry , Praseodymium/analysis , Praseodymium/chemistry , Reference Standards , Reproducibility of Results , Samarium/analysis , Samarium/chemistry , Scandium/analysis , Scandium/chemistry , Spectrophotometry, Atomic/instrumentation , Strontium/chemistry , Sulfates/chemistry , Terbium/analysis , Terbium/chemistry , Ytterbium/analysis , Ytterbium/chemistryABSTRACT
This paper describes the determination of trace Zr and Hf in the sample using carbon powder and titanium oxide as the buffer by Atomic Emission Spectrometry (AES). Titanium was selected for the internal standard line. Sample separation and chemical treatment were not required. The sample was directly loaded into an ordinary electrode. The method is simple, rapid and accurate. The conditions for the determination, and the factors of influence have been studied. A new method has been developed for the determination of zirconium and hafnium. The analytical lines of Zr and Hf were 327.3 and 286.6 nm respectively. The internal standard line of Ti was 308.8 nm. The linear range of the determination of Zr and Hf was 0-0.50% and 0-0.25% respectively. The detection limit of Zr and Hf was 0.0010% and 0.010% respectively. The range of the recovery of zirconium and hafnium was 96.67%-105.0%. The results for these elements in standard sample are in agreement with certified values with a precision of 3.61% RSD for Zr (n = 9), and 4.82% RSD for Hf (n = 9). The method has been applied to the determination of Zr and Hf with satisfactory results.
